3.1 AS Level

Electronegativity and bonding

8 flashcards to master this topic

Definition Flip

Define electronegativity.

Answer Flip

Electronegativity is the power of an atom to attract the electron density in a covalent bond towards itself.

Key Concept Flip

Explain how nuclear charge affects electronegativity.

Answer Flip

A greater nuclear charge (more protons) leads to a stronger attraction for electrons, thus increasing electronegativity. The positive charge of the nucleus is more effective at attracting electrons.

Key Concept Flip

Explain how atomic radius affects electronegativity.

Answer Flip

A larger atomic radius means the valence electrons are further from the nucleus, experiencing weaker attraction. This decreases the atom's ability to attract electrons in a bond, thus reducing electronegativity.

Key Concept Flip

Explain how electron shielding affects electronegativity.

Answer Flip

Increased shielding from inner electron shells reduces the effective nuclear charge felt by valence electrons. This weakens the attraction for electrons in a bond, thus decreasing electronegativity.

Key Concept Flip

State the trend in electronegativity across a period of the Periodic Table, and explain why.

Answer Flip

Electronegativity generally increases across a period (left to right). This is because nuclear charge increases while shielding remains relatively constant, leading to a stronger attraction for bonding electrons.

Key Concept Flip

State the trend in electronegativity down a group of the Periodic Table, and explain why.

Answer Flip

Electronegativity generally decreases down a group. This is because atomic radius and shielding increase, reducing the effective nuclear charge felt by bonding electrons and thus weakening the attraction.

Key Concept Flip

Using Pauling electronegativity values, how can you predict whether a bond will be ionic or covalent?

Answer Flip

A large difference in electronegativity (typically > 1.7) between two atoms indicates a likely ionic bond, where one atom strongly attracts the electrons from the other. A small difference indicates a covalent bond with shared electrons.

Calculation Flip

Given the Pauling electronegativity values of Na (0.93) and Cl (3.16), predict the type of bond formed between them.

Answer Flip

The electronegativity difference between Na and Cl is 3.16 - 0.93 = 2.23, which is greater than 1.7. Therefore, a strong ionic bond is predicted.

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2.3 Formulas 3.2 Ionic bonding