Electronegativity and bonding
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Define electronegativity.
Electronegativity is the power of an atom to attract the electron density in a covalent bond towards itself.
Explain how nuclear charge affects electronegativity.
A greater nuclear charge (more protons) leads to a stronger attraction for electrons, thus increasing electronegativity. The positive charge of the nucleus is more effective at attracting electrons.
Explain how atomic radius affects electronegativity.
A larger atomic radius means the valence electrons are further from the nucleus, experiencing weaker attraction. This decreases the atom's ability to attract electrons in a bond, thus reducing electronegativity.
Explain how electron shielding affects electronegativity.
Increased shielding from inner electron shells reduces the effective nuclear charge felt by valence electrons. This weakens the attraction for electrons in a bond, thus decreasing electronegativity.
State the trend in electronegativity across a period of the Periodic Table, and explain why.
Electronegativity generally increases across a period (left to right). This is because nuclear charge increases while shielding remains relatively constant, leading to a stronger attraction for bonding electrons.
State the trend in electronegativity down a group of the Periodic Table, and explain why.
Electronegativity generally decreases down a group. This is because atomic radius and shielding increase, reducing the effective nuclear charge felt by bonding electrons and thus weakening the attraction.
Using Pauling electronegativity values, how can you predict whether a bond will be ionic or covalent?
A large difference in electronegativity (typically > 1.7) between two atoms indicates a likely ionic bond, where one atom strongly attracts the electrons from the other. A small difference indicates a covalent bond with shared electrons.
Given the Pauling electronegativity values of Na (0.93) and Cl (3.16), predict the type of bond formed between them.
The electronegativity difference between Na and Cl is 3.16 - 0.93 = 2.23, which is greater than 1.7. Therefore, a strong ionic bond is predicted.
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