1. Overview
Radioactive decay is a random process, meaning we cannot predict when a single nucleus will decay. However, because samples contain billions of atoms, we can use the concept of half-life to predict how the overall activity of a sample decreases over time. Understanding half-life is crucial for using radiation safely in medicine, industry, and the home.
Key Definitions
- Half-life ($t_{1/2}$): The time taken for half the nuclei of a specific isotope in a sample to decay. Alternatively: the time taken for the activity (or count rate) of a sample to decrease to half its initial value.
- Activity: The rate at which a source of unstable nuclei decays, measured in Becquerels (Bq). 1 Bq = 1 decay per second.
- Isotope: Atoms of the same element with the same number of protons but different numbers of neutrons.
- Count-rate: The number of decays detected per second by a device (like a Geiger-Müller tube).
- Background Radiation: The low-level radiation present at all times from natural (e.g., rocks, cosmic rays) and man-made sources.
Core Content
Understanding Half-life Since decay is exponential, a substance never "runs out" of radioactivity linearly. Instead, it halves every set period of time.
- After 1 half-life: 50% remains (1/2)
- After 2 half-lives: 25% remains (1/4)
- After 3 half-lives: 12.5% remains (1/8)
Using Decay Curves A decay curve is a graph showing Activity (y-axis) against Time (x-axis).
To find half-life from a graph:
- Pick a starting activity on the y-axis.
- Find the time value for that activity.
- Divide the starting activity by 2.
- Find the new time value for this halved activity.
- The difference between these two times is the half-life.
Worked Example (Core) Question: A sample has an initial activity of 1200 Bq. Its half-life is 5 minutes. What is the activity after 15 minutes?
- Calculate the number of half-lives: $15 \div 5 = 3$ half-lives.
- Halve the activity three times:
- 1200 $\rightarrow$ 600 (1st half-life)
- 600 $\rightarrow$ 300 (2nd half-life)
- 300 $\rightarrow$ 150 Bq (3rd half-life)
Extended Content (Extended Curriculum Only)
Calculating Half-life with Background Radiation In real experiments, a Geiger-Müller tube detects both the source and the background radiation. To find the true half-life, you must subtract the background radiation first.
Formula: $Corrected Activity = Measured Activity - Background Radiation$
Worked Example (Extended) Question: The background radiation is 20 counts/min. A source measures 180 counts/min initially. After 4 hours, the source measures 60 counts/min. Calculate the half-life.
- Find initial corrected activity: $180 - 20 = 160$ counts/min.
- Find final corrected activity: $60 - 20 = 40$ counts/min.
- Determine half-lives: $160 \rightarrow 80 \rightarrow 40$ (This is 2 half-lives).
- Calculate duration: 2 half-lives = 4 hours, so 1 half-life = 2 hours.
Applications of Isotopes The choice of isotope depends on its penetrating power and its half-life.
| Application | Radiation Type | Preferred Half-life | Reasoning |
|---|---|---|---|
| Smoke Alarms | Alpha | Long (years) | Alpha is easily blocked by smoke; long half-life means you don't need to replace the source often. |
| Irradiating Food | Gamma | Long | Gamma kills bacteria/mold throughout the food; long half-life provides a consistent dose over time. |
| Sterilising Equipment | Gamma | Long | Gamma penetrates packaging to kill bacteria on medical tools; long half-life ensures the machine stays effective. |
| Thickness Control | Beta | Long | Alpha is too weak (blocked by paper); Gamma is too strong. Beta absorption changes based on thickness; long half-life ensures changes in count-rate are due to metal thickness, not source decay. |
| Cancer Treatment | Gamma | Short/Long | Focused beams kill tumors. If injected, a short half-life is needed to limit the dose to the patient. |
| Medical Diagnosis | Gamma | Very Short (hours) | Must be penetrating to leave the body; short half-life ensures the patient isn't radioactive for long. |
Key Equations
- Number of half-lives ($n$): $n = \frac{\text{Total Time}}{\text{Half-life duration}}$
- Remaining Activity ($A$ ): $A = A_0 \times (\frac{1}{2})^n$ (where $A_0$ is initial activity)
- Corrected Activity: $A_{corrected} = A_{measured} - A_{background}$
- Units: Activity = Becquerels (Bq); Time = Seconds, minutes, hours, or years.
Common Mistakes to Avoid
- ❌ Wrong: Assuming a substance decays at a constant linear rate (e.g., if 100g decays to 50g in 10 mins, it will all be gone in 20 mins).
- ✓ Right: Decay is exponential. After 20 minutes, 25g would remain (half of 50g).
- ❌ Wrong: Calculating half-life by simply dividing the total time by the starting activity.
- ✓ Right: Use the total time to find how many "halving cycles" occurred.
- ❌ Wrong: Forgetting to subtract background radiation before halving the numbers in extended questions.
- ✓ Right: Subtract background radiation from all readings first, then perform the half-life calculation.
Exam Tips
- Read the Graph Axes: Ensure you are looking at "Activity" or "Count-rate" and check the units for time (hours vs. days).
- The "Half-way" Check: If a question asks for the activity after a certain time, always draw a quick arrow diagram ($100 \rightarrow 50 \rightarrow 25$) to keep track of how many half-lives have passed.
- Application Logic: When asked why a specific isotope is used, always mention two things: its penetrating power (can it get through the material?) and its half-life (safety vs. convenience).