2.1 AS Level

Relative masses of atoms and molecules

Cambridge A-Level Chemistry (9701)  · Unit 2: Atoms, molecules and stoichiometry  · 7 flashcards

Relative masses of atoms and molecules is topic 2.1 in the Cambridge A-Level Chemistry (9701) syllabus , positioned in Unit 2 — Atoms, molecules and stoichiometry , alongside The mole and the Avogadro constant and Formulas.  In one line: The unified atomic mass unit (u) is defined as one-twelfth of the mass of a carbon-12 atom. It is used as a standard unit for measuring the mass of atoms and molecules.

Marked as AS Level: examined at AS Level in Paper 1 (Multiple Choice), Paper 2 (AS Structured Questions) and Paper 3 (Advanced Practical Skills). The same content may also be assumed in Paper 4 (A Level Structured Questions).

The deck below contains 7 flashcards — 5 definitions and 2 key concepts — covering the precise wording mark schemes reward.  Use the 5 definition cards to lock down command-word answers (define, state), then move on to the concept and calculation cards to handle explain, describe, calculate and compare questions.

Key definition

The unified atomic mass unit (u)

The unified atomic mass unit (u) is defined as one-twelfth of the mass of a carbon-12 atom. It is used as a standard unit for measuring the mass of atoms and molecules.

Example: The mass of one hydrogen atom is approximately 1u.

What the Cambridge 9701 syllabus says

2025-2027 syllabus, in our words · AS Level

What the syllabus expects you to be able to do in this topic, in plain English. For the exact wording, see the official syllabus (PDF).

  1. Define one unified atomic mass unit (u) as 1/12 the mass of a single carbon-12 atom.
  2. Define relative formula mass, relative molecular mass (Mᵣ), relative atomic mass (Aᵣ) and relative isotopic mass, each measured against unified atomic mass units.

Cambridge syllabus keywords to use in your answers

These are the official Cambridge 9701 terms tagged to this section. Mark schemes credit responses that use the exact term — weave them into your answers verbatim rather than paraphrasing.

unified atomic mass unit carbon-12 atom relative atomic mass relative isotopic mass relative molecular mass relative formula mass

Tips to avoid common mistakes in Relative masses of atoms and molecules

Definition Flip

Define the unified atomic mass unit (u).

Answer Flip

The unified atomic mass unit (u) is defined as one-twelfth of the mass of a carbon-12 atom. It is used as a standard unit for measuring the mass of atoms and molecules.

Example: The mass of one hydrogen atom is approximately 1u.
Definition Flip

Define relative atomic mass (Ar).

Answer Flip

Relative atomic mass (Ar) is the weighted average mass of the naturally occurring isotopes of an element, relative to one-twelfth of the mass of a carbon-12 atom. It is a dimensionless quantity.

Example: Ar of chlorine is 35.5
Definition Flip

Define relative isotopic mass.

Answer Flip

Relative isotopic mass is the mass of an isotope relative to one-twelfth of the mass of a carbon-12 atom. It is a dimensionless quantity.

Example: The relative isotopic mass of Carbon-14 is approximately 14.
Definition Flip

Define relative molecular mass (Mr).

Answer Flip

Relative molecular mass (Mr) is the weighted average mass of a molecule compared with one-twelfth of the mass of an atom of carbon-12. It has no units. In practice it is found by adding the relative atomic masses of all the atoms in the molecule.

Example: Mr of H₂O = 2(1.0) + 16.0 = 18.0.
Definition Flip

Define relative formula mass.

Answer Flip

Relative formula mass is the weighted average mass of one formula unit of a compound (for example an ionic compound) compared with one-twelfth of the mass of an atom of carbon-12. It has no units and is found by adding the relative atomic masses of the atoms in the formula.

Example: relative formula mass of NaCl = 23.0 + 35.5 = 58.5.
Key Concept Flip

Explain the relationship between relative atomic mass (Ar) and the unified atomic mass unit (u).

Answer Flip

Relative atomic mass (Ar) is a ratio. It represents how many times heavier, on average, an atom of an element is compared to 1/12th the mass of a carbon-12 atom (1 u). Therefore, it is dimensionless.

Key Concept Flip

Describe how relative atomic mass (Ar) is calculated from isotopic abundance data.

Answer Flip

Ar = Σ (isotopic mass × % abundance) / 100. Multiply the mass of each isotope by its percentage abundance, sum the results, and divide by 100 to account for the percentage. This calculates the weighted average.

More Chemistry flashcards

Browse every 9701 flashcard topic by syllabus area.

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More topics in Unit 2 — Atoms, molecules and stoichiometry

Relative masses of atoms and molecules sits alongside these A-Level Chemistry decks in the same syllabus unit. Each uses the same spaced-repetition system, so progress in one informs the next.

Key terms covered in this Relative masses of atoms and molecules deck

Every term below is defined in the flashcards above. Use the list as a quick recall test before your exam — if you can't define one of these in your own words, flip back to that card.

The unified atomic mass unit (u)
Relative atomic mass (Ar)
Relative isotopic mass
Relative molecular mass (Mr)
Relative formula mass

How to study this Relative masses of atoms and molecules deck

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